Terahertz (THz) radiation (0.1 THz to 10 THz) falls in between the infrared and microwave region of the electromagnetic spectrum, and it shares some properties with each of these, as shown below. The terahertz region is of particular scientific importance due to its remarkable and unique characteristics. Many common materials and living tissues are semi-transparent and have ‘THz fingerprints’, permitting them to be imaged, identified, and analyzed. Meanwhile, the non-ionizing properties of terahertz radiation and the relatively low power levels used indicate that it is safe. Terahertz radiation constitutes a gap in the science and remains to be better understood and much better exploited.
Coherent Control of Optical Spin-to-Orbital Angular Momentum Conversion in Metasurface ×
Huifang Zhang, Ming Kang, Xueqian Zhang, Wengao Guo, Changgui Lv, Yanfeng Li, Weili Zhang, and Jiaguang Han
Published in: Advanced Materials
（Volume 29, Issue 6, 1604252）
Abstract Efficient control over the conversion of optical angular momentum from spin to orbital form in a metasurface system is achieved. Under coherent symmetric incidence, it can support nearly 100% conversion and unitary output, while it can support 50% conversion with 25% transmittance under one beam incidence.
Quan Xu, Xueqian Zhang, Yuehong Xu, Chunmei Ouyang, Zhen Tian, Jianqiang Gu, J. Li, S. Zhang, Jiaguang Han, and Weili Zhang
Published in: Laser Photonics & Reviews
（Volume 11, Issue 1, 1600212）
Abstract The ability of generating arbitrary surface plasmon (SP) profiles in a controllable manner is of particular interest in designing plasmonic imaging, lithography and forcing devices. During the past decades, holography has gained enormous interest and achievements in free‐space three‐dimensional displays. Here, by applying a two‐dimensional version of holography, we experimentally demonstrate a generic method to control the SP profiles. Through controlling the orientation angles of two separated slits under circular polarization incidence, the amplitude and phase of the excited SPs can be freely manipulated, which allows direct generation of the desired SP profiles. A series of controllable SP holography schemes are theoretically and experimentally demonstrated, where the holographic SP profiles with high imaging quality can be dynamically modulated by varying the circular polarization handedness or orientation angle of linear polarization. The universality and simplicity of the proposed design strategies would offer promising opportunities for practical plasmonic applications.
Unexpectedly Enhanced Solubility of Aromatic Amino Acids and Peptides in an Aqueous Solution of Divalent Transition-Metal Cations ×
Guosheng Shi, Yaru Dang, Tingting Pan, Xing Liu, Hui Liu, Shaoxian Li, Lijuan Zhang, Hongwei Zhao, Shaoping Li, Jiaguang Han, Renzhong Tai, Yiming Zhu, Jichen Li, Qing Ji, R. A. Mole, Dehong Yu, and Haiping Fang
Published in: Physical Review Letters
（Volume 117, Issue 23, 238102）
Abstract We experimentally observed considerable solubility of tryptophan (Trp) in a CuCl2 aqueous solution, which could reach 2–5 times the solubility of Trp in pure water. Theoretical studies show that the strong cation-π interaction between Cu2+ and the aromatic ring in Trp modifies the electronic distribution of the aromatic ring to enhance significantly the water affinity of Trp. Similar solubility enhancement has also been observed for other divalent transition-metal cations (e.g.,
Zn2+ and Ni2+), another aromatic amino acid (phenylalanine), and three aromatic peptides (Trp-Phe, Phe-Phe, and Trp-Ala-Phe).
Monolayer graphene sensing enabled by the strong Fano-resonant metasurface ×
Quan Li, Longqing Cong, Ranjan Singh, Ningning Xu, Wei Cao, Xueqian Zhang, Zhen Tian, Liangliang Du, Jiaguang Han, and Weili Zhang
Published in: Nanoscale
（Volume 8, Issue 39, 17278-17284）
Abstract Recent advances in graphene photonics reveal promising applications in the technologically important terahertz spectrum, where graphene-based active terahertz metamaterial modulators have been experimentally demonstrated. However, the sensitivity of the atomically thin graphene monolayer towards sharp Fano resonant terahertz metasurfaces remains unexplored. Here, we demonstrate thin-film sensing of the graphene monolayer with a high quality factor terahertz Fano resonance in metasurfaces consisting of a two-dimensional array of asymmetric resonators. A drastic change in the transmission amplitude of the Fano resonance was observed due to strong interactions between the monolayer graphene and the tightly confined electric fields in the capacitive gaps of the Fano resonator. The deep-subwavelength sensing of the atomically thin monolayer graphene further highlights the extreme sensitivity of the resonant electric field excited at the dark Fano resonance, allowing the detection of an analyte that is λ/1 000 000 thinner than the free space wavelength.
Pancharatnam–Berry Phase Induced Spin-Selective Transmission in Herringbone Dielectric Metamaterials ×
Mitchell Kenney, Shaoxian Li, Xueqian Zhang, Xiaoqiang Su, Teun-Teun Kim, Dongyang Wang, Dongmin Wu, Chunmei Ouyang, Jiaguang Han, Weili Zhang, Hongbo Sun, and Shuang Zhang
Published in: Advanced Materials
（Volume 28, Issue 43, 9567-9572）
Abstract A dielectric metamaterial approach for achieving spin‐selective transmission of electromagnetic waves is proposed. The design is based on spin‐controlled constructive or destructive interference between propagating phase and Pancharatnam–Berry phase. The dielectric metamaterial, consisting of monolithic silicon herringbone structures, exhibits a broadband operation in the terahertz regime.
Anisotropic coding metamaterials and their powerful manipulation of differently polarized terahertz waves ×
Shuo Liu, Tie Jun Cui, Quan Xu, Di Bao, Liangliang Du, Xiang Wan, Wen Xuan Tang, Chunmei Ouyang, Xiao Yang Zhou, Hao Yuan, Hui Feng Ma, Wei Xiang Jiang, Jiaguang Han, Weili Zhang, and Qiang Cheng
Published in: Light: Science & Applications
（Volume 5, e16076）
Abstract Metamaterials based on effective media can be used to produce a number of unusual physical properties (for example, negative refraction and invisibility cloaking) because they can be tailored with effective medium parameters that do not occur in nature. Recently, the use of coding metamaterials has been suggested for the control of electromagnetic waves through the design of coding sequences using digital elements '0' and '1,' which possess opposite phase responses. Here we propose the concept of an anisotropic coding metamaterial in which the coding behaviors in different directions are dependent on the polarization status of the electromagnetic waves. We experimentally demonstrate an ultrathin and flexible polarization-controlled anisotropic coding metasurface that functions in the terahertz regime using specially designed coding elements. By encoding the elements with elaborately designed coding sequences (both 1-bit and 2-bit sequences), the x- and y-polarized waves can be anomalously reflected or independently diffused in three dimensions. The simulated far-field scattering patterns and near-field distributions are presented to illustrate the dual-functional performance of the encoded metasurface, and the results are consistent with the measured results. We further demonstrate the ability of the anisotropic coding metasurfaces to generate a beam splitter and realize simultaneous anomalous reflections and polarization conversions, thus providing powerful control of differently polarized electromagnetic waves. The proposed method enables versatile beam behaviors under orthogonal polarizations using a single metasurface and has the potential for use in the development of interesting terahertz devices.
Asymmetric excitation of surface plasmons by dark mode coupling ×
Xueqian Zhang, Quan Xu, Quan Li, Yuehong Xu, Jianqiang Gu, Zhen Tian, Chunmei Ouyang, Yongmin Liu, Shuang Zhang, Xixiang Zhang, Jiaguang Han, and Weili Zhang
Published in: Science Advances
（Volume 2, Issue 2, e1501142）
Abstract Control over surface plasmons (SPs) is essential in a variety of cutting-edge applications, such as highly integrated photonic signal processing systems, deep-subwavelength lasing, high-resolution imaging, and ultrasensitive biomedical detection. Recently, asymmetric excitation of SPs has attracted enormous interest. In free space, the analog of electromagnetically induced transparency (EIT) in metamaterials has been widely investigated to uniquely manipulate the electromagnetic waves. In the near field, we show that the dark mode coupling mechanism of the classical EIT effect enables an exotic and straightforward excitation of SPs in a metasurface system. This leads to not only resonant excitation of asymmetric SPs but also controllable exotic SP focusing by the use of the Huygens-Fresnel principle. Our experimental findings manifest the potential of developing plasmonic metadevices with unique functionalities.
Abstract Anomalous launch of a surface wave with different handedness phase control is achieved in a terahertz metasurface based on phase discontinuities. The polarity of the phase profile of the surface waves is found to be strongly correlated to the polarization handedness, promising polarization‐controllable wavefront shaping, polarization sensing, and environmental refractive‐index sensing.
Abstract It is extremely challenging to control the phase of light at will in free space. Here, Pancharatnam–Berry‐phase‐enabled, tunable phase control of free‐space light is experimentally demonstrated in an ultrathin flexible dispersion‐free metadevice. This metadevice enables the broadband conversion of linearly polarized light into any desired output polarization.
Abstract A metasurface‐based terahertz flat‐lens array is proposed, comprising C‐shaped split‐ring resonators exhibiting locally engineerable phase discontinuities. Possessing a high numerical aperture, the planar lens array is flexible, robust, and shows excellent focusing characteristics in a broadband terahertz frequency. It could be an important step towards the development of planar terahertz focusing devices for practical applications.
Active graphene–silicon hybrid diode for terahertz waves ×
Quan Li, Zhen Tian, Xueqian Zhang, Ranjan Singh, Liangliang Du, Jianqiang Gu, Jiaguang Han, and Weili Zhang
Published in: Nature Communications
（Volume 6, 7082）
Abstract Controlling the propagation properties of the terahertz waves in graphene holds great promise in enabling novel technologies for the convergence of electronics and photonics. A diode is a fundamental electronic device that allows the passage of current in just one direction based on the polarity of the applied voltage. With simultaneous optical and electrical excitations, we experimentally demonstrate an active diode for the terahertz waves consisting of a graphene-silicon hybrid film. The diode transmits terahertz waves when biased with a positive voltage while attenuates the wave under a low negative voltage, which can be seen as an analogue of an electronic semiconductor diode. Here, we obtain a large transmission modulation of 83% in the graphene-silicon hybrid film, which exhibits tremendous potential for applications in designing broadband terahertz modulators and switchable terahertz plasmonic and metamaterial devices.
Manifestation of PT Symmetry Breaking in Polarization Space with Terahertz Metasurfaces ×
Mark Lawrence, Ningning Xu, Xueqian Zhang, Longqing Cong, Jiaguang Han, Weili Zhang, and Shuang Zhang
Published in: Physical Review Letters
（Volume 113, Issue 9, 093901）
Abstract By utilizing the vector nature of light as well as the inherent anisotropy of artificial meta-atoms, we investigate parity time symmetry breaking in polarization space using a metasurface with anisotropic absorption, whose building blocks consist of two orthogonally orientated meta-atoms with the same resonant frequency but different loss coefficients. By varying their coupling strength, we directly observe a phase transition in the eigenpolarization states of the system, across which the long axis of the eigenpolarization ellipses experience a sudden rotation of 45°. Despite the lack of rotational symmetry of the metasurface, precisely at the phase transition, known as the exceptional point, the eigenmodes coalesce into a single circularly polarized state. The PT symmetric metasurfaces are experimentally implemented at terahertz frequencies.
Abstract By combining the freedom of both the structural design and the orientation of split ring resonator antennas, we demonstrate terahertz metasurfaces that are capable of controlling both the phase and amplitude profiles over a very broad bandwidth. As an example, we show that the phase‐amplitude metasurfaces can be engineered to control the diffraction orders arbitrarily.
Longqing Cong, Ningning Xu, Jianqiang Gu, Ranjan Singh, Jiaguang Han and Weili Zhang
Published in: Laser Photonics Reviews
（Volume 8, Issue 4, 626-632）
Abstract Metamaterials offer exciting opportunities that enable precise control of light propagation, its intensity and phase by designing an artificial medium of choice. Inducing birefringence via engineered metamolecules presents a fascinating mechanism to manipulate the phase of electromagnetic waves and facilitates the design of polarimetric devices. In this paper, a high‐efficiency, broadband, tunable and flexible quarter‐wave plate based on a multilayer metamaterial is presented. Excellent achromatic π/2 phase retardance with high transmission is observed upon terahertz propagation through the quarter‐wave plate. The calculated Stokes parameter represents the output polarization state numerically, indicating an excellent broadband conversion of linearly polarized light into circularly polarized light. The metamaterial‐based quarter‐wave plate demonstrated in this work could be an important step forward in the development of functional terahertz polarization conversion devices for practical applications.
Abstract A terahertz metasurface is reported to exhibit broadband anomalous deflection with strong phase discontinuities. Weili Zhang, Jiaguang Han, Zhen Tian, and co-workers demonstrate on page 4567 that various frequency components ranging from 0.43 to 1.0 THz with polarization orthogonal to the incidence are deflected into a broad range of angles covering 25° to 84° under normal incidence. Based on this metasurface, a thin Fresnel zone plate was consequently developed that is capable of focusing terahertz radiation within a broad frequency range.
Broadband plasmon induced transparency in terahertz metamaterials ×
Zhihua Zhu, Xu Yang, Jianqiang Gu, Jun Jiang, Weisheng Yue, Zhen Tian, Masayoshi Tonouchi, Jiaguang Han, and Weili Zhang
Published in: Nanotechnology
（Volume 24, Issue 21, 214003）
Abstract Plasmon induced transparency (PIT) could be realized in metamaterials via interference between different resonance modes. Within the sharp transparency window, the high dispersion of the medium may lead to remarkable slow light phenomena and an enhanced nonlinear effect. However, the transparency mode is normally localized in a narrow frequency band, which thus restricts many of its applications. Here we present the simulation, implementation, and measurement of a broadband PIT metamaterial functioning in the terahertz regime. By integrating four U-shape resonators around a central bar resonator, a broad transparency window across a frequency range greater than 0.40 THz is obtained, with a central resonance frequency located at 1.01 THz. Such PIT metamaterials are promising candidates for designing slow light devices, highly sensitive sensors, and nonlinear elements operating over a broad frequency range.
Active control of electromagnetically induced transparency analogue in terahertz metamaterials ×
Jianqiang Gu, Ranjan Singh, Xiaojun Liu, Xueqian Zhang, Yingfang Ma, Shuang Zhang, Stefan A. Maier, Zhen Tian, Abul K. Azad, Hou-Tong Chen, Antoinette J. Taylor, Jiaguang Han, and Weili Zhang
Published in: Nature Communications
（Volume 3, 1151）
Abstract Recently reported metamaterial analogues of electromagnetically induced transparency enable a unique route to endow classical optical structures with aspects of quantum optical systems. This method opens up many fascinating prospects on novel optical components, such as slow light units, highly sensitive sensors and nonlinear devices. In particular, optical control of electromagnetically induced transparency in metamaterials promises essential application opportunities in optical networks and terahertz communications. Here we present active optical control of metamaterial-induced transparency through active tuning of the dark mode. By integrating photoconductive silicon into the metamaterial unit cell, a giant switching of the transparency window occurs under excitation of ultrafast optical pulses, allowing for an optically tunable group delay of the terahertz light. This work opens up the possibility for designing novel chip-scale ultrafast devices that would find utility in optical buffering and terahertz active filtering.
Abstract A large scale homogenous invisibility cloak functioning at terahertz frequencies is reported. The terahertz invisibility device features a large concealed volume, low loss, and broad bandwidth. In particular, it is capable of hiding objects with a dimension nearly an order of magnitude larger than that of its lithographic counterpart, but without involving complex and time‐consuming cleanroom processing.